The pigment is made up of mainly pigment powder with a small amount of the polyol Part A which means when adding the pigment, you should always add it to part A, to avoid any reaction occurring.
Due to the fact that only a very small amount of the weight of the pigment is resin (Part A), and pigment pastes are only added at low percentages themselves, it is generally not necessary to adjust the mix ratio of the resin when adding a pigment and so you should mix - for example: (100g resin part A + 5g pigment) with (100g resin part B).